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REE recovery from end-of-Life NdFeB permanent magnet scrap: A critical review

机译:报废钕铁硼永磁废料中的稀土回收:一项重要评论

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摘要

NdFeB permanent magnets have different life cycles, depending on the applications: from as short as 2–3 years in consumer electronics to 20–30 years in wind turbines. The size of the magnets ranges from less than 1 g in small consumer electronics to about 1 kg in electric vehicles (EVs) and hybrid and electric vehicles (HEVs), and can be as large as 1000–2000 kg in the generators of modern wind turbines. NdFeB permanent magnets contain about 31–32 wt% of rare-earth elements (REEs). Recycling of REEs contained in this type of magnets from the End-of-Life (EOL) products will play an important and complementary role in the total supply of REEs in the future. However, collection and recovery of the magnets from small consumer electronics imposes great social and technological challenges. This paper gives an overview of the sources of NdFeB permanent magnets related to their applications, followed by a summary of the various available technologies to recover the REEs from these magnets, including physical processing and separation, direct alloy production, and metallurgical extraction and recovery. At present, no commercial operation has been identified for recycling the EOL NdFeB permanent magnets and the recovery of the associated REE content. Most of the processing methods are still at various research and development stages. It is estimated that in the coming 10–15 years, the recycled REEs from EOL permanent magnets will play a significant role in the total REE supply in the magnet sector, provided that efficient technologies will be developed and implemented in practice.
机译:钕铁硼永磁体的寿命因应用而异:从消费类电子产品的短至2-3年到风力涡轮机的20-30年不等。磁铁的大小范围从小型消费电子产品的不到1克到电动汽车(EV)以及混合动力和电动汽车(HEV)的约1千克,在现代风力发电机中可以达到1000-2000千克涡轮机。 NdFeB永磁体包含约31–32 wt%的稀土元素(REE)。从使用寿命终止(EOL)产品中回收这种类型的磁铁中所含的稀土元素,将在未来的稀土元素总供应中发挥重要的补充作用。然而,从小型消费电子产品中收集和回收磁体带来了巨大的社会和技术挑战。本文概述了与其应用相关的NdFeB永磁体的来源,然后总结了从这些磁体中回收稀土元素的各种可用技术,包括物理加工和分离,直接合金生产以及冶金提取和回收。目前,尚未发现用于回收EOL NdFeB永磁体和回收相关REE含量的商业运营。大多数加工方法仍处于各种研发阶段。据估计,在未来10到15年中,如果能够在实践中开发和实施高效的技术,则EOL永磁体的再生稀土将在磁体行业的稀土总供应中发挥重要作用。

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